Magnetic Study on Hexagonal Nitrides of 3d Transition Metals
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概要
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Magnetic and Mossbauer effect measuremdnts on the nitrides with hcp metal lattice of V, Cr, Mn and Fe are carried out as a function of composition. Hexagonal VN_x and hexagonal CrM_x are Pauli paramagnetic. Hexagonal MnN_x shows antiferromagnetism, while both hexagonal and orthorhombic FeN_x show ferromagnetism at low temperatures. In these Phases, nitrogen atoms suppress magnetic ordering in consequence of the reduction of magnetic moments. As a whole, the observed types of magnetism of hexagonal nitrides resemble those of their metals in spite of the difference in crystal structures. Type II superconductivity is found in hexagonal VN_x although it is not yet conclusive.
- 社団法人日本物理学会の論文
- 1972-07-05
著者
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Mekata Mamoru
Chemistry Department Faculty Of Science Kyoto University
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YOSHIMURA Hiroshi
Chemistry Department, Faculty of Science, Kyoto University
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TAKAKI Hideo
Chemistry Department, Faculty of Science, Kyoto University
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Takaki Hideo
Chemistry Department Faculty Of Science Kyoto University
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YOSHIMURA Hiroshi
Chemistry Department, Faculty of Science, Kyoto University:(Present address) Sendai Branch of Sony Coop.