Proton Conduction through Solid Alcohols due to Molecular Rotation.

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概要

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• The anomalous electric conductivity in higher normal alcohols is often attributed to the proton transfer accompanied by the rotation of molecules around their long axis. The direct experimental justification for the above idea is attempted, where results are described in the following. The gas produced as the result of the electric conduction is identified spectroscopically with hydrogen, and its amount is found to coincide with the expected value, assuming that the current is conducted, solely by protons. The effect of the added long chain compounds is observed and the result seems to be well understood on the basis of the proton-transfer-and-molecular-rotation mechanism.

• 社団法人日本物理学会の論文
• 1951-10-25

著者

• Kakiuchi Yoshinobu

  Institute For Solid State Physics University Of Tokyo

• Komatsu Hachiro

  Institute Of Science And Technology Tokyo University

• KYOYA Susumu

  Institute of Science and Technology, University of Tokyo

• Kyoya Susumu

  Institute Of Science And Technology University Of Tokyo

関連論文

• Nuclear Magnetic Resonance in Some Crystalline Polymers
• Proton Magnetic Resonance Absorption in Hydrogen Perchlorate Monohydrate and the Structure of the Oxonium Ion I.
• An Abnormal Saturation Behavior in High Resolution Proton Magnetic Resonance Spectra
• Anomalous Specific Heat and Molecular Rotation in Normal Alcohols.
• X-ray Studies on Cetyl Alcohols
• Proton Conduction through Solid Alcohols due to Molecular Rotation.
• Proton Magnetic Resonance Absorption in Hydrogen Perchlorate Monohydrate and the Structure of the Oxonium Ion II
• Proton Magnetic Resonance Absorption Spectra of Long Chain Normal Primary Alcohol of Probable Carbon Number 32
• Anomalous Specific Heat and Molecular Rotation in Solid Normal Hexadecyl Alcohol
• On the Electret.
• Anomalous Specific Heat and Molecular Rotation in Solid Normal Hexadecyl Alcohol

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