Interaction between Polyions and Low Molecular Ions

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概要

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• The characteristic nature of ion-binding of much charged polyions has been investigated mainly on the basis of the Poisson-Boltzmann (P.B.) equation and partly through the conductance experiment. In general, the ion-binding can be classified into two types, the φ-binding and the P-binding. The former is due to the electrostatic field around polyions, while the latter is due to the short-range interaction between ionized groups of polyions and salt-ions. Through the theoretical analysis of non-linear property of the P.B. equation, we have found, for every shape of polyions, the strong φ-binding of counterions which greatly depresses the polyion-charge within a thin ion-condensation phase around the polyion.

• 社団法人日本物理学会の論文
• 1961-04-05

著者

• Imai Nobuhisa

  Faculty Of Science Nagoya University

関連論文

• Interaction between Polyions and Low Molecular Ions

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