Indirect Nuclear Spin-Spin Couplings in Saturated Hydrocarbon Molecules

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概要

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• A general formula for the coupling constant J_<HH'> between two hydrogen nuclei is derived by means of the valence bond method. Almost all the structures, which are obtained by Rumer's theorem, are taken into account. The calculated value of J_<HH'> in a methane molecule is 12.1 sec.^<-1>, which is in good agreement with experiment. It is shown that an approximate formula for J_<HH'>, which is derived from the general one, is convenient to discuss the qualitative behavior of J_<HH'>.

• 社団法人日本物理学会の論文
• 1960-02-05

著者

• HIROIKE Eiko

  Department of Physics, Tokyo Institute of Technology

• Hiroike Eiko

  Department of Chemistry, Faculty of Science, Tohoku University

関連論文

• Indirect Nuclear Spin-Spin Couplings in Saturated Hydrocarbon Molecules
• Theory of Indirect Dephasing for a Vibrating Molecule in Dense Mediums.III
• Effect of Electron Correlation on Long-Range Proton Ssin-Spin Couplings in Saturated Hydrocarbon Molecules

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