X-ray Study on Molecular Rotation in Tetragonal Ammonium Nitrate
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Hindered rotation of nitrate groups in the tetragonal ammonium nitrate was studied by using X-ray diffuse scattering. The first, second, third and fourth order diffuse scatterings of plate-like shape perpendicular to the C^*-direction in the reciprocal lattice were observed. These diffuse scatterings were analyzed referring to the crystal structure as determined previously by using Laue-Bragg scattering. It was found that the correlation among rotating nitrate groups is strong in the C-direction, while it is weak in the direction perpendicular to it and its type is different from that to be expected from the lower temperature modification.
- 社団法人日本物理学会の論文
- 1959-12-05
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関連論文
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