Equation of State for Vapor-Liquid-Solid System

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概要

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• Generalizing the idea of order-disorder in the alloy theory, we can calculate the unified equation of state for a lattice gas with many interstitial sublattices in the degree of approximation similar to that developed by Bragg-Williams. For n=9 (n is the number of sublattices), the concrete equation of state is estimated and the ratio of the number of molecules belonging to each sublattice to their total number is given as a function of molecular density. Then the critical temperature and density for vapor-liquid transition are estimated for n=4, 9, 16. Furthermore, it is shown that the density region in the stable liquid phase is very narrow for n=4, but that it becomes wider for n=9, 16.

• 社団法人日本物理学会の論文
• 1955-10-05

著者

• Shimose Ikuro

  Faculty Of Literature And Science Yamaguchi University

関連論文

• Equation of State for Vapor-Liquid-Solid System
• Lattice Theory of Liquid State
• Statistical Theory of Phase Transition. II Numerical Calculation for Lattice Gas
• Statistical Theory of Phase Transition III : Application to Vapor-Liquid-Solid Equilibrium
• Statistical Theory of Phase Transition. I General Theory for Lattice Gas

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