Proton Transfer in Hydrogen Bond and Its Participation in π-Electron Systems

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概要

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• The infrared spectra of OH or NH groups in hydrogen bonds in 3μ region are divided into two (or three) types according to their wavelengths and intensities. The first group is of the alcoholic type, and the second group is observed when conjugated π-electron systems combine the hydrogen bonds and when the effect of the proton transfer across the hydrogen bond and the "Antenna Effect" are important. Qualitative discussions on the proton transfer are developed and numerical calculations are carried out with simple symmetrical double minimum potentials. The linear combination method solving such problems is shown to be numerically incorrect, though it is convenient for a qualitative consideration. Further evidence and biological importance of the hydrogen transfer participating n-electron systems are discussed.

• 社団法人日本物理学会の論文
• 1955-10-05

著者

• Ooshika Yuzuru

  Kobayashi Institute Of Physical Research

• Oshida Isao

  Kobayashi Institute Of Physical Research

• Miyasaka Reikiti

  Kobayasi Institute Of Physical Research

関連論文

• The W.K.B. Method for the Differential Equations of the Fourth Order
• Absorption Spectra of Dyes in Solution
• A Semi-empirical Theory of the Conjugated Systems : II. Bond Alternation in Conjugated Chains
• Theory of Electrochemical Diodes
• Proton Transfer in Hydrogen Bond and Its Participation in π-Electron Systems
• LCAO-MO Treatment of Phthalocyanine
• A New Graphical Solution of Ordinary Linear Differential Equation of the Second Order
• Hydration of Ions and Coordinate Bond
• A Semi-empirical Theory of the Conjugated Systems : I. General Formulation
• Photogalvanic Cells with Ion-Exchanger Membrane Electrolytes

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