Electrical and Optical Properties of Poly (p-phenylene) Film and Their Doping Effect
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概要
- 論文の詳細を見る
Poly(p-phenylene) films with a conductivity of co. 100 S/cm are synthesized by anew method of electrical oxidation of benzene using the composite electrolytes ofCuCl./LiAsF.. An in situ study of the absorption spectra of the poly(p-phenylene)films during the electrochemical doping with AsF. has been carried out. From the ab-sorption spectrum of undoped state, we find a strong absorption peak at ca. 3.4 eVwhich is associated with the transition from ground-state to excited-state. Theremarkable changes of the absorption spectra below the photon energy of 3.0 eV areobserved, which are related to the polaron and/or bipolaron states of this polymer.The electrochemical n-type doping is also demonstrated.
- 社団法人日本物理学会の論文
- 1986-04-15
著者
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YOSHINO Katsumi
Department of Electronic Engineering, Graduate School of Engineering, Osaka University
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Satoh M
Tohoku Univ. Sendai Jpn
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KANETO Keiichi
Department of Computer Science and Electronics, Kyushu Institute of Technology
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Satoh M
Muroran Inst. Technology Muroran
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Kaneto Keiichi
Department Of Computer Science And Electronics Kyushu Institute Of Technology
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Satoh Masaharu
Department Of Electrical Engineering Faculty Of Engineering Osaka University
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Yoshino Katsumi
Department Of Electrical Engineering Faculty Of Engineering Osaka University
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Kaneto K
Faculty Of Engineering Osaka University
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TABATA Munehiro
Department of Electrical Engineering,Faculty of Engineering,Osaka University
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Tabata Munehiro
Device Engineering Development Center Matsushita Electric Industrial Co. Ltd.
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Kaneto Keiichi
Department of Biological Functions and Engineering, Graduate School of Life Sciences and Systems Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu, Kitakyushu 808-0196, Japan
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