Pseudo-Jahn-Teller Effect in Ferrohemoglobin Due to (3d)^6-(3d)^5(4p) Interaction by an A_<2u> Vibrational Mode

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概要

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• The triggerjng mechanism at the transition from the 7'-conformation to 7?-conformation in the Hemoglobin is attributed to the pseudo-Jahn-Teller effectresulting from the intra-atomic (3d)'-(3d)'(4p) interaction by an A.. vibrationalmode. The general formula for this effect in ton-porphyrins as well as metallo-porphyrins is given by the closure approximation. The explicit adiabatic poten-fiats of the iron for the te",iary two conformations (t- and r-conformation) aregiven.

• 社団法人日本物理学会の論文
• 1983-01-15

著者

• Mizuhashi Seiji

  Applied Science Department The University Of Eletro-communications

関連論文

• Pseudo-Jahn-Teller Effect in Ferrohemoglobin Due to (3d)^6-(3d)^5(4p) Interaction by an A_ Vibrational Mode
• A_ Out-of-Plane Vibration of Iron-Porphin Compound

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