Analysis of the Intensity Distribution in the near Ultraviolet Absorption Spectrum of Benzene

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概要

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• Intensities of the fine structure in the electronic transition A_<1g>-A_<2u> allowed through molecular vibrations in the ground or excited state, are analyzed within the first order approximation in the electron-vibration interaction, processes of the simultaneous emission or absorption of one q antum or several quanta of the vibration being considered. In the analysis three parameters are chosen ; one is the ratio of the two electron-vibration coupling constants and the others are parameters associated with the structure of benzene in the excited state. The result is in good agreement with the experiment.

• 社団法人日本物理学会の論文
• 1970-12-05

著者

• Kakitani Toshiaki

  Research Institute For Fundamental Physics Kyoto University

関連論文

• Analysis of the Intensity Distribution in the near Ultraviolet Absorption Spectrum of Benzene
• Theoretical Study of Optical Absorption Curves of Molecules. IV : Improvement of Self-Consistent HMO Method Using a New Resonance Integral and Investigation of a Relation between Bond Alternation and Wavelength of Optical Absorption
• Theoretical Study of Optical Absorption Curves of Molecules. II : Effect of the Vibrational Mode-Mode Interaction in the Excited State

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