Plane Steady Navier-Stokes Detonations of Oxyozone

概要

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Structure of plane steady detonation waves propagating with Chapman-Jouguet velocity is analysed in consideration of transport phenomena. For rich mixtures of oxyozone, only O_3+X&roaar;O_2+O+X and O+O_3⇾O_2+O_2 have to be considered in the analysis as associated elementary reactions, where numerical integrations can be carried out from hot boundary to cold boundary singularities since the hot boundary constitutes a nodal singularity due to the first-order character of reaction. Detonation solutions are found out for arbitrarily lean mixtures. For lean mixtures, on the other hand, the inclusion of the recombination reaction O+O_2+X⇾O_3+X becomes necessary and consequently the reaction order near the hot boundary is raised from the first to the second. The examination of such hot boundary presents non-existence of the integration curve satisfying both boundary conditions.
社団法人日本物理学会の論文
1970-05-05