The Dipole-Polarization Potential in H_2-Electron System

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概要

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• The adiabatic polarization potential in the system of hydrogen molecule and an electron is calculated by a variation perturbation method in two-center prolate spheroidal coordinates. In this calculation, a 16-term James-Coolidge type wave function is used for obtaining the dipole contribution to the potential. This is the first detailed calculation of the polarization potential of a diatomic molecule in two-center coordinates. The asymptotic forms of the dipole polarization potential in the direction parallel and perpendicular to the molecular axis are -5.975/5r^4 and -4.359/2r^4 in atomic units, respectively. The numerators of these asymptotic forms are to be compared with the exact values of the dipole polarizabilities 6.38049 and 4.55769 a. u. obtained by Kolos and Wolniewicz.

• 社団法人日本物理学会の論文
• 1969-11-05

著者

• Hara Shunsuke

  Space Science Department Institute Of Space And Aeronautical Science University Of Tokyo

関連論文

• The Dipole-Polarization Potential in H_2-Electron System
• The Scattering cf Slow Electrons by Hydrogen Molecules
• Rotational Excitation of H_2 by Slow Electrons

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