A Note on the Theory of the High Polymer Solution

スポンサーリンク

概要

• 論文の詳細を見る

• The free energy of mixing' of the dilute high polymer solution is calculated by a new approximational method which may clarify how the interaction between the solvent and the solute molecules should be taken into account. It is based on the idea somewhat analogous to the cage model theory of the liquid state and may be considered to unite the quasi-lattice model theory and the gas-like model theory. But it does not use the idea of the potential of the average force as in Zimm's theory. The osmotic pressure formula is derived and it is shown that the second osmotic coefficient depends explicitly on the solvent-segment interaction through a complicated function even in the simplest case where the solute molecule may be expressed with the rigid sphere with the well type attraction potential.

• 社団法人日本物理学会の論文
• 1952-04-25

著者

• Ichimura Hiroshi

  Tokyo Institute Of Technology

関連論文

• A Note on the Theory of the High Polymer Solution

スポンサーリンク