Topographic Study of Ferroelectric NaNO_2 Crystals. II. : Mechanism of Polarization Reversal
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概要
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X-ray topographic study was made of a sodium nitrite (NaNO_2) single crystal which had been partially polarized with an external d.c. electric field at room temperature. Images with characteristic diffraction contrast found in topographs of the crystal suggest the following process of polarization reversal. By increasing thickness of pre-existing domain boundary walls the intermediate state regions having the same crystal structure as that of the domain boundary walls, are formed first, and on the next step the intermediate state regions once formed are eroded by the domains having the right direction of polarization. Rotation of NO_2 redicals by 180° around their O-O axes will be the molecular mechanism of the polarization reversal under electric field at room temperature.
- 社団法人日本物理学会の論文
- 1972-05-05
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