The Orbital Paramagnetism in Transition Metals and Their Alloys : N,. Cr Metals and Ni-Cu, Cr-V, and Ti-V Alloys
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概要
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The orbital paramagnetic susceptibilities (χ_orb) in Ni and Cr metals are calculated based on Kubo-Obata's theory and using the energy band calculated by Fletcher in Ni metal, the energy band calculated by Asdente and Friedel, and the one modified by Lomer in Cr metal. With the assumption of rigid band model, χ_orb In Ni-Cu and Cr-V alloys are calculated. The calculated values are in fair agreement with those obtained by Shimizu et. al. The temperature dependence of χ_orb is also calculated. In Ni metal and Ni-Cu alloys, we find appreciable temperature dependence of χ_orb and that χ_so is not negligible. In Cr metal and Cr-V alloys, χ_orb is nearly temperature independent. Finally, the diamagnetic susceptibilities due to 3d and 4s electrons are estimated to be small, and the field dependence of susceptibilities is discussed.
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- 1965-08-05