Schrodinger's Equation for a System of Particles

概要

論文の詳細を見る
A simple and unlform treatment is presented for eliminatlng the Angular variables from the n-particle Schrodinger equation and for deriving the Hamiltonian of polyatomic molecules in a form suitable for a perturbation calculation. The Hamiltonian is first set up conveniently in a special set of rotating axes. Introduction of three pseudo-momenta, which correspond to no coordinates, greatly simplifies the calculation and makes it unnecessary to evaluate the Jacobian of the transformation, The Hamiltonian so obtained can be directly used to eliminate the angular variables. For the molecular problem it is found necessary to pass on to some other rotating frame in which the coupling between rotation and vibration becomes sufficiently small. A method for doing this is discussed in the last section.
社団法人日本物理学会の論文
1965-03-05