A Statistical-Mechanical Theory of Surface Tension of Curved Surface Layer I
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概要
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Combining with a thermodynamical definition, an extension of Harasima's statistical-mechanical method to calculate the plane surface tension leads to general expressions for the surface tension of cylindrical and spherical interface. A new definition of "surface of tension" is introduced and the familiar Kelvin relation is derived more strictly by using this definition than by the traditional method. From the point of view of this definition Tolman's conclusion on the curvature dependency of surface tension turns out to be questionable and necessary to be reexamined.
- 一般社団法人日本物理学会の論文
- 1955-05-05