Generalized Kinetics of Chemical Change : Some Conditions for Validity of the Steady State Approximation

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概要

• 論文の詳細を見る

• Equations based on an expansion around the equilibrium state are not particularly useful for treating chemical systems of general interest to chemists. However, equations that neglect potential reversibility when systems are far from equilibrium initially do not reduce to equilibrium conditions at long times. By classifying each chemical species as reactant, product or intermediate, generalized equations can be developed to describe the time dependent behavior of any homogeneous uniform closed chemical system. Applicability of the method is illustrated by developing necessary and sufficient conditions for validity of the steady state approximation for systems in which all intermediates are free radicals.

• 理論物理学刊行会の論文
• 1979-04-01

著者

• Noyes Richard

  Department Of Chemistry University Of Oregon

• NOYES Richard

  Department of Chemistry, University of Oregon

関連論文

• Generalized Kinetics of Chemical Change : Some Conditions for Validity of the Steady State Approximation

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