Fe-30Cr-50Ni-2Mo 合金の高温クリープ抵抗に及ぼす Cr 相の影響(<特集>新しい耐熱鋼)

概要

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A new corrosion resistant Fe-50%Ni-30%Cr-2%Mo austenitic alloy developed for super heaters has a high creep rupture strength at temperatures as high as 1073 K. The creep rupture strength of this alloy is equivalent to that of 17-14CuMo, one of the strongest commercial alloys. Unlike ordinary commercial austenitic heat resisting steels strengthened by carbide dispersion, which tend to decrease in the creep rupture strength at higher testing temperatures and under lower creep stresses, this alloy retains its strength in a temperature range between 823 and 1073 K for more than 10000 h. This excellent long term creep rupture strength was found to be due to a high density and a uniform dispersion of intragranular precipitates of bcc chromium phase. The dispersion strengthening due to the bcc chromium was unambiguously demonstrated by a creep test of a preaged specimen with a controlled dispersion of the precipitates. Coarsening of the intragranular bcc chromium precipitates was slower than that of the carbides, which lead to the smaller decrease in the creep rupture strength at higher testing temperatures and under lower creep stresses.
社団法人日本鉄鋼協会の論文
1990-07-01