溶融マグネシウム-珪素浴による鉄鋼の珪素浸透法

概要

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A molten magnesium-silicon alloy bath containing 1 to 12 mass% of silicon was used for siliconizing iron by keeping the specimen in the bath for 180-900s at 973-1123K. The composition of siliconized layer, which consisted of finegrained and columnar-grained sublayers, was identified almost the same as Fe_3Si, using the Energy Dispersive Spectrometer and the X-ray Diffractometer. Micro-Vickers hardness number of the layer was about 500. The thickness of the layer varied with the siliconizing temperature and time. Then the diffusion coefficient was calculated as, D=1.91×10^<-4>exp[-152.6(kJ/mol)/RT](m^2/s) for Mg-3%Si alloy bath, and D=4.54×10^<-4>exp[-163.5(kJ/mol)/RT](m^2/s) for Mg-12%Si alloy bath. On the growing way of the columnar-grained sublayer which is thicker than the fine-grained sublayer, insoluble particles deposited on the surface of the specimen can be taken and dispersed into the layer by this siliconizing process.
社団法人日本鉄鋼協会の論文
1997-07-01