Synthetic Photochemistry. LXVIII. Singlet-Oxyggen Oxidation of Fusicoccadienes. In-vitro-Conversion to Mould Metabolites

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概要

• 論文の詳細を見る

• With an oxidation with singlet oxygen, both fusicocca-2(6),3-diene and fusicocca-2,5-diene, biogenetic precursors of some oxygenated 5-8-5-membered tricyclic diterpenoids, respectively afforded the sole endoperoxides, stereospecifically. These endoperoxides were isomerized thermally under very mild conditions to bisepoxides and keto epoxides. These transformations constitute biogenetic type synthesis of fusicogigantepoxides and fusicogigantones.

• 九州大学の論文

著者

• Kato Nobuo

  Interdisciplinary Graduate School of Engineering Sciences Kyushu University

• Nakanishi Kohji

  Interdisciplinary Graduate School Of Engineering Sciences Kyushu University

• Nishikawa Hideyuki

  Interdisciplinary Graduate School of Engineering Sciences Kyushu University

関連論文

• Synthetic Photochemistry. LXXI. Photocycloaddition of Methyl 2,4-Dioxohexanoate to 3-Benzylozy-2-methylpropene
• Mercurophilic 1-(8,8-Dicyanoheptafulven-3-yl)aza-15-crown-5 Ether. Synthesis, X-Ray Structural Analysis, and Fixation of Its Derivative on a Polymer
• Synthetic Photochemistry. LXVIII. Singlet-Oxyggen Oxidation of Fusicoccadienes. In-vitro-Conversion to Mould Metabolites

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