<原報>温度滴定法によるアミンの中和熱測定
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概要
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An attempt was made to determine the neutralization heat of amines with the thermometric titration method as the acid-base reactions with hydrochloric acid. In this study, two apparatus (Cobble automatic thermoanalyser, Takara differential temperature detector) were employed, and titrations have been carried out at room temperature. The latter was available to eliminate the effects of heats of dilution and mixing. Ethanol-water was used as solvent in case of weak bases. It was found that the heats of neutralization of aliphatic, aromatic and hydroxy amines was 13.2,6.9∿9.5,and 8.3∿12kcal/mole respectively.
- 共立薬科大学の論文
- 1972-11-30
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