<PAPRE>A Kinetic Study on The Chemiluminescent Reaction in The Ultraviolet Laser Photolysis of HN_3

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概要

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• Dispersed emission spectra of the chemiluminescence were recorded in the uv photolysis of hydrogen azide (HN_3), and assigned to electronic transitions of NH_2(A^2A_1-X^2B_l). It is found that the vibrationally excited NH_2(A) is produced in the reaction of vibrationally excited NH(a^lΔ) with HN_3. The rate constants for the production of various vibrational levels of amidogen, NH_2(A), and their dependence on photolysis wavelength were determined. The potential energy surface governing thereaction NH(a) + HN_3 was derived.

• 神戸市立工業高等専門学校の論文
• 1998-02-28

著者

• 山崎 勝義

  新潟大学理学部化学科

• 渡辺 昭敬

  応用化学科

関連論文

• A Kinetic Study on The Chemiluminescent Reaction in The Ultraviolet Laser Photolysis of HN_3

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