Metathesis-Mediated Synthesis of (R)-10-Methyl-2-tridecanone, the Southern Corn Rootworm Pheromone
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概要
- 論文の詳細を見る
(<I>R</I>)-10-Methyl-2-tridecanone, the female sex pheromone of the southern corn rootworm (<I>Diabrotica</I> <I>undecimpunctata</I> <I>howardi</I> Barber), was synthesized in 9 steps from methyl (<I>S</I>)-3-hydroxy-2-methylpropanoate in a 15.7% overall yield. Olefin cross metathesis between (<I>R</I>)-6-methyl-1-nonene and 5-hexen-2-one employing Grubbs’ first-generation catalyst was the key step of the synthesis.
- Japan Society for Bioscience, Biotechnology, and Agrochemistryの論文
- 2012-02-23
著者
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Mori Kenji
Photosensitive Materials Res. Center Toyo Gosei Co. Ltd.
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SHIKICHI Yasumasa
Photosensitive Materials Research Center, Toyo Gosei Co., Ltd.
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