Synthesis of L,L-Lactide via Depolymerization of Oligo(L-Lactic Acid) by Microwave Irradiation
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概要
- 論文の詳細を見る
Lactide production and racemization under microwave irradiation are compared with those under conventional heating. The amount of lactide including L,L-, D,D-, and meso-lactides that was produce in the reaction mixtures under microwave irradiation at 25 mmHg and 180°C for 12 h was almost 2.7 times the corresponding amount produced under conventional heating. The ratio of the number of meso-lactide to the total number of lactides was higher under microwave irradiation than under conventional heating by a factor of 8.9. These differences between lactide production under microwave irradiation and that under conventional heating became increasingly noticeable as the reaction time and temperature increased. However, it was observed that at pressures under 15 mmHg, the ratio of the number of meso-lactide to the total number of lactides under microwave irradiation was decreased and became equal to the corresponding value under conventional heating.
- 社団法人 化学工学会の論文
- 2009-12-01
著者
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Ohara Hitomi
R&d Center For Bio-based Materials Kyoto Institute Of Technology
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Ohara Hitomi
R&D Center for Bio-based Materials, Kyoto Institute of Technology
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Hirao Koichi
R&d Center For Bio-based Materials Kyoto Institute Of Technology
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HIRAO Koichi
R&D Center for Bio-based Materials, Kyoto Institute of Technology
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MASUTANI Kazunari
R&D Center for Bio-based Materials, Kyoto Institute of Technology
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Hirao Koichi
R & D Center For Bio-based Materials Kyoto Institute Of Technology
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Masutani Kazunari
R&d Center For Bio-based Materials Kyoto Institute Of Technology
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0hara Hitomi
R&D Center for Bio-Based Materials, Kyoto Institute of Technology
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- Synthesis of L,L-Lactide via Depolymerization of Oligo(L-Lactic Acid) by Microwave Irradiation
- Synthesis of L,L-Lactide via Depolymerization of Oligo(L-Lactic Acid) by Microwave Irradiation