New Approaches in Precise Synthesis of Polyolefins Containing Polar Functionalities by Olefin Copolymerizations Using Transition Metal Catalysts

スポンサーリンク

概要

• 論文の詳細を見る

• Recent successful examples for synthesis of new polyolefins containing polar functionalities by adopting the approaches by (a) direct copolymerization of olefin with polar monomer using living radical or coordination insertion methods, (b) direct alkane C-H activation/functionalization (post functionalization of polyolefins), and by (c) controlled incorporation of reactive functionalities (and the subsequent introduction of polar funtionalities under mild conditions) by coordination polymerization in the presence of transition metal complex catalysts have been described. In particular, our recent efforts for precise synthesis of polyolefins containing polar functionalities by (i) efficient incorporation of reactive functionality by copolymerization of ethylene with nonconjugated diene using nonbridged half-titanocene catalysts and (ii) subsequent chemical modifications under mild conditions have been introduced.

• 社団法人 有機合成化学協会の論文
• 2010-11-01

著者

• Nomura Kotohiro

  Department Of Chemistry Graduate School Of Science And Engineering Tokyo Metropolitan University

関連論文

• New Approaches in Precise Synthesis of Polyolefins Containing Polar Functionalities by Olefin Copolymerizations Using Transition Metal Catalysts

スポンサーリンク