Hydrothermal stability of mesoporous Ni-doped γ-Al_2O_3
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概要
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Ni-doped γ-Al2O3 with different molar compositions has been synthesized on α-Al2O3 porous supports by the sol-gel method using nitrate-alkoxide precursors. The increasing of lattice constants by Ni doping showed the formation of uniform solid solution. When the Ni content increased up to 10 mol%, NiO phase was formed. The relationship between molar compositions and hydrothermal stability under atmosphere of steam/N2 = 3 at 773 K for 0-50 h was compared. The pore size distribution of 5 mol% Ni-doped γ-Al2O3 on α-Al2O3 porous support was stable even after hydrothermal exposure at 773 K for 50 h.
- 公益社団法人 日本セラミックス協会の論文
- 2009-07-01
著者
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TAKAHASHI Seiji
Japan Fine Ceramics Center
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NAGANO Takayuki
Environmental Material Department, Materials Research and Development Laboratory, Japan Fine Ceramic
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SATO Koji
Environmental Material Department, Materials Research and Development Laboratory, Japan Fine Ceramic
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SAITOH Tomohiro
Nanoscopy & Simulation Department, Nanostructures Research Laboratory, Japan Fine Ceramics Center
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TAKAHASHI Seiji
Environmental Material Department, Materials Research and Development Laboratory, Japan Fine Ceramic
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Nagano Takayuki
Environmental Material Department Materials Research And Development Laboratory Japan Fine Ceramics
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Takahashi Seiji
Environmental Material Department Materials Research And Development Laboratory Japan Fine Ceramics
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Saitoh Tomohiro
Nanoscopy & Simulation Department Nanostructures Research Laboratory Japan Fine Ceramics Center
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Nagano Takayuki
Environmental Material Dep. Materials Res. And Dev. Lab. Japan Fine Ceramics Center
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Sato Koji
Environmental Material Department Materials Research And Development Laboratory Japan Fine Ceramics
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