Physical and electric properties of lead-free (Na_<0.5>K_<0.5>)NbO_3-Ba(Zr_<0.04>Ti_<0.96>)O_3 ceramics

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概要

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• Extending the investigations on (Na0.5K0.5)NbO3-based solid solution for lead-free piezoelectric ceramics, this paper consider the complex solid-solution system (Na0.5K0.5)NbO3-Ba(Zr0.04Ti0.96)O3 [NKN-BZT]. (Na0.5K0.5)NbO3 with 0-10 mol% Ba(Zr0.04Ti0.96)O3 has been prepared following the conventional mixed oxide process. X-ray diffraction analysis revealed that, during sintering, all of the Ba(Zr0.04Ti0.96)O3 diffuses into the lattice of (Na0.5K0.5)NbO3 to form a solid solution. Only a orthorhombic phase with a perovskite structure was found in this system. It was found that the samples with a low content of Ba(Zr0.04Ti0.96)O3 exhibit relatively good physical and electric properties. For 0.98 (Na0.5K0.5)NbO3-0.02Ba(Zr0.04Ti0.96)O3 ceramics, the electromechanical coupling coefficients of the planar mode kp and the thickness mode kt reach 0.26 and 0.52, respectively, at the sintering of 1100°C for 2 h. The ratio of thickness coupling coefficient to planar coupling coefficient is 2. For 0.98(Na0.5K0.5)NbO3-0.02Ba(Ti0.96Zr0.04)O3 ceramics, the electromechanical coupling coefficients of the planar mode kp and the thickness mode kt reach 0.3 and 0.55, respectively, at the sintering of 1100°C for 5 h. With suitable Ba(Zr0.04Ti0.96)O3 concentration and sintering condition, good physical and electric properties were obtained. Our results show that 0.98(Na0.5K0.5)NbO3-0.02Ba(Zr0.04Ti0.96)O3 solid solution ceramics are one of the promising lead-free ceramics for high frequency electromechanical transducer applications.

• 公益社団法人 日本セラミックス協会の論文
• 2009-05-01

著者

• Wang Chun-huy

  Department Of Electronic Engineering Nan-jeon Institute Of Technology

• Wang Chun-huy

  Department Of Electronic Engineering Nan-jeon Institute Of Technolog

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