Subsolidus phase relations in the Bi_4Ti_3O_<12>-Ag/Ag_2O-TiO_2 system
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概要
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The subsolidus phase relations in the Bi4Ti3O12-Ag/Ag2O-TiO2 system were determined by means of solid-state reaction, X-ray diffraction and scanning electron microscopy. The rutile and anatase phases showed different chemistries when reacting with the Ag/Ag2O-Bi2O3, and the Ag0.5Bi8.5Ti7O27 phase can be obtained from the anatase form but not from the rutile form. In the present study the phase relations in the Bi-Ag-Ti-O system were established for the rutile form. The solid solutions TiO2SS, Bi4Ti3O12SS and Bi2Ti2O7SS were identified in the Bi4Ti3O12-Ag/Ag2O-TiO2 system and silver was found to be compatible with all three. There was no compatibility between the silver and the Bi2Ti4O11. A single-phase compound was obtained for the pyrochlore phase Bi1.55Ag0.1Ti2O6.375.
- 公益社団法人 日本セラミックス協会の論文
- 2009-04-01
著者
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Hu Xing
Department of Cardiology, The Second Xiangya Hospital, Central South University
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Hu Xing
Department Of Electronic Materials Science And Engineering South China University Of Technology
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Hu Xing
Department Of Cardiology The Second Xiangya Hospital Central South University
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SKAPIN Sreco
Advanced Materials Department, Jozef Stefan Institute
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SUVOROV Danilo
Advanced Materials Department, Jozef Stefan Institute
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Suvorov Danilo
Advanced Materials Department Jozef Stefan Institute
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Skapin Sreco
Advanced Materials Department Jozef Stefan Institute
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