Phase Separation Transition in Liquids and Polymers Induced by Electric Field Gradients
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概要
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Spatially uniform electric fields have been used to induce instabilities in liquids and polymers, and to orient and deform ordered phases of block-copolymers. Here we discuss the demixing phase transition occurring in liquid mixtures when they are subject to spatially nonuniform fields. Above the critical value of potential, a phase-separation transition occurs, and two coexisting phases appear separated by a sharp interface. Analytical and numerical composition profiles are given, and the interface location as a function of charge or voltage is found. The possible influence of demixing on the stability of suspensions and on inter-colloid interaction is discussed.
- 2009-04-15
著者
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Marcus Gilad
Max-planck-institut Fur Quantenoptik
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Tsori Yoav
Department of Chemical Engineering, Ben-Gurion University of the Negev, 84105 Beer-Sheva, Israel