Kinetics of the Cationic Polymerization of Isobutylene for Planning and Process Intensification of an Industrial Plant

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概要

• 論文の詳細を見る

• Isobutylene is polymerized in a p-dicumylchloride (p-DCC)/titanium tetrachloride (TiCl4)/2-methylpyridine (α-picoline) initiating system and kinetic data for planning and process intensification of an industrial plant is acquired through the measurement of temperature and simple trial-and-error calculation. As a result, the propagation rate decreases with increasing temperature in appearance, and its mechanism should be significantly governed by the dissociation equilibrium of the end of the polymer chain. In addition, the effects of the mixing ratio of solvent, TiCl4 concentration and α-picoline concentration are investigated and discussed.

• 社団法人 化学工学会の論文
• 2009-07-01

著者

• Kawachi Hideo

  Process Dev. Laboratories Healthcare Products Business Unit Kaneka Corp.

• Kawachi Hideo

  Process Development Laboratories Healthcare Products Business Unit Kaneka Corp.

• WACHI Shun

  Process Technology & Research Group, Process Technology Laboratories, Production Technology Division

• Wachi Shun

  Process Technology & Research Group Process Technology Laboratories Production Technology Divisi

関連論文

• Crystallization of Ergosterol from Hexane Solution by a Continuous Column Crystallizer Equipped with a Water Feeding System
• Kinetics of the Cationic Polymerization of Isobutylene for Planning and Process Intensification of an Industrial Plant

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