Catalysis Mechanism Study of Potassium Salts on Cellulose Pyrolysis by Using TGA-FTIR Analysis
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概要
- 論文の詳細を見る
The catalytic effect of three kinds of potassium salts on cellulose pyrolysis kinetics and products was studied on a thermogravimetric analyzer coupled with a Fourier transform infrared spectroscopy. Experimental results showed that potassium salts catalyzed the dehydration and depolymerization reactions in the initial pyrolysis stage, enhanced the release of oxygenated gases, intensively catalyzed the formation of char, and restrained the production of volatiles. Kinetic modeling showed that the presence of potassium ions provided a mechanistic route with lower activation energy, and accelerated the pyrolysis rate. Both KCl and K2CO3 restrained the release of levoglucosan, glycoaldehyde and C=O containing compounds, while K2SO4 largely promoted the formation of levoglucosan. The presence of KCl and K2CO3 might have retarded the unzipping reaction at the terminal units of the cellulose chain, and thus restrained the formation of levoglucosan. K2SO4 exhibited different catalytic mechanisms, which uniquely catalyzed the formation of levoglucosan.
- 社団法人 化学工学会の論文
- 2008-12-01
著者
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Liu Qian
State Key Laboratory Of High Performance Ceramics And Superfine Microstructure Shanghai Institute Of
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Liu Qian
State Key Laboratory Of Clean Energy Utilization Zhejiang University
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Cen Kefa
State Key Laboratory Of Clean Energy Utilization Zhejiang University
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Cen Kefa
State Key Lab Of Clean Energy Utilization Zhejiang University
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Wang Shurong
State Key Laboratory Of Clean Energy Utilization Zhejiang University
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LUO Zhongyang
State Key Laboratory of Clean Energy Utilization, Zhejiang University
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Luo Zhongyang
State Key Laboratory Of Clean Energy Utilization Zhejiang University
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Cen Kefa
State Key Laboratory of Clean Energy Utilization, Zhejiang University
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