Observation of Lithium Isotope Effect Accompanying Electrochemical Insertion of Lithium into Zinc
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概要
- 論文の詳細を見る
Lithium was electrochemically inserted into zinc from the mixed solution of ethylene carbonate and methyl ethyl carbonate containing 1 M LiClO4, and the lithium isotope effect accompanying the insertion was investigated. The x value of LixZn after the electrolysis ranged from 0.013 to 0.139. The single-stage separation factor, S, ranged from 1.005 to 1.023 with the lighter isotope, 6Li, being preferentially fractionated into the zinc phase. The present results on lithium isotope effect qualitatively agreed with calculated results based on the molecular orbital theory.
- 社団法人 日本原子力学会の論文
- 2008-05-01
著者
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OI Takao
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Oi Takao
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Mouri Masahiro
Department of Cardiovascular Medicine, Kyushu University Graduate School of Medical Sciences
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Mouri Masahiro
Department Of Chemistry Sophia University
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Mouri Masahiro
Department Of Cardiovascular Medicine Kyushu University Graduate School Of Medical Sciences
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Yanase Satoshi
Department Of Chemistry Sophia University
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Oi Takao
Sophia Univ. Tokyo Jpn
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Yanase Satoshi
Samsung Yokohama Res. Inst. Kanagawa Jpn
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