The First Resonance Hybrid of Silyl-Carbene and Pyridyl-Silylene Complexes : Formation by Aryl C-H Bond Activation of DMAP [4-(Dimethylamino)pyridine] on a Silylene Complex

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概要

• 論文の詳細を見る
• 2007-05-05

著者

• Tobita Hiromi

  Department Of Chemistry Graduate School Of Science Tohoku University

• Komuro Takashi

  Department Of Chemistry Graduate School Of Science Tohoku University

• BEGUM Rockshana

  Department of Chemistry, Graduate School of Science, Tohoku University

• Begum Rockshana

  Department Of Chemistry Graduate School Of Science Tohoku University

関連論文

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• Synthesis of New Paramagnetic Heterodinuclear Complexes with Dithiolene Bridging Ligands, (Ph_2C_2S_2)Fe(Cp'Ru)(μ-Ph_2C_2S_2)_2(Cp'= η^5-C_5H_4SiMe_3(Cp^),η^5-C_5Me_5(Cp^*)), by Replacement of a Metal Fragment
• Kinetic Study of the Skeletal Inversion in a Tetrairon-Sulfur Cluster {η^5-C_5H_4(SiMe_3)}_4Fe_4S_6
• Isolation and Structural Characterization of Complexes Formed in the Reactions of [{C_5H_4(SiMe_3)}_2Fe_2(CO)_4] and [{1,3-C_5H_3(SiMe_3)_2}_2Fe_2(CO)_4] with Elemental Sulfur
• Light- and Heat-Induced Geometric Isomerization of Chloro(hydrido)iridium(III) Complex Containing a (2-Phosphinoethyl)silyl Chelate Ligand
• Synthesis, Structure, and Properties of Three- and Six-Membered Metallacycles Composed of Iron, Germanium, and Sulfur Atoms
• Synthesis and Structure of a Base-stabilized Silyl(silylene)tantalum Complex
• Cluster Core Expansion through Incorporation of Transition-metal Fragments or an Alkyne Molecule into an Incomplete Cubane-type Fe_2RuS_4 Cluster
• Synthesis and Characterization of Triplet Germylene-bridged Diiron Complexes and Singlet Stannylene-bridged Diiron Complexes
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• Dehydrogenative Coupling of Monohydrosilanes Mediated by (2-Phosphinoethyl)silylrhodium(I) Complex
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• Synthesis and Properties of s-Alkyl-Substituted Silanediyl-Bridged and Silanetriyl-Bridged Diiron Complexes, Cp_2(CO)_2Fe_2(μ-CO)[μ-Si(X)CHR_2]and Cp_2(CO)_2Fe_2(μ-CO)[μ-Si(DMAP)CHR_2]^+I^- (X = H, I; R = Et, Ph; DMAP = 4-(Dimethylamino)pyridine)
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• Reactivity of Alkoxy-bridged Bis(silylene)iron Complexes
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• Reversible 1, 2-Migration of Aryl Groups on Silyl Ligands : Formation and Properties of Silylenetungsten Complexes Stabilized by an External Base
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