含窒素ヘテロ環カルベンを触媒としたホモエノラートの極性転換反応
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概要
- 論文の詳細を見る
Polarity inversion (umpolung or charge affinity inversion) of functional groups is widely recognized as a powerful and efficient synthetic method because it makes possible not only to offer strategic flexibilities but also to form carbon-car-bon bonds in the design of complex molecules. Recently, the new approaches of carbonyl synthons employing <I>N</I>-hetero-cyclic carbene catalyzed homoenolate reactions have been utilized in a variety of applications. In this review, the chemistry highlight in development of the catalytic generation of homoenolates and their application to the novel carbon-car-bon bond-forming process is described.
- 社団法人 有機合成化学協会の論文
- 2007-10-01