Synthesis of GeFe_<1.4> Nanoparticles Using the Transformation of Iron Trisoxalategermanium Metal Coordination Nanopolymers by Solid Phase Reduction

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概要

• 論文の詳細を見る

• In this communication, we demonstrate the novel preparation of alloy metal nanoparticles using a nanometer-sized metal coordination polymer (MCNP) as a precursor. The presented method works effectively for the construction of an uncommon alloy nanoparticle such as a IV semiconductor-transition metal alloy. Iron trisoxalategermanium MCNPs stabilized by stealylamine (SA) were newly synthesized in reverse micelle technique, and Ge-ox-Fe-SA was successfully transformed into GeFe1.4 alloy metal nanoparticles by a gas phase reduction of metal sites under H2, accompanied by the removal of the bridging oxalate ligands. The prepared GeFe1.4 nanoparticles exhibited unique ferromagnetic behavior.

• 社団法人 電気学会の論文
• 2007-09-01

著者

• Yamada Mami

  Tokyo University Of Agriculture And Technology

• Yamada Mami

  Tokyo University Of Agriculture And Technology Department Of Applied Chemistry

• Miyake Mikio

  Japan Advanced Institute Of Science And Technology

• OHKAWA Ryuji

  Japan Advanced Institute of Science and Technology

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