Decomposition of Monochlorobiphenyl by Grinding with Rare Earth Oxides
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概要
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Co-grinding of monochlorobiphenyl (BP-Cl) with rare earth oxides has been conducted and the mechanochemical decomposition of BP-Cl on the oxides has been investigated by a suite of analytical methods including X-ray diffraction (XRD), thermogravimetry (TG), Raman spectroscopy, electron spin resonance (ESR), gas chromatography/mass spectrometry (GC/MS). The experimental results have been compared with the use of CaO as additive and the differences have been discussed. It has been found that the use of rare earth oxides allows an efficient decomposition of BP-Cl and the time required to complete the decomposition reaction is much shorter than that by the use of CaO.
- 2006-04-01
著者
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TANAKA Yasumitsu
RMC, MSNC, Sony Sendai Technology Center, Sony Corp.
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ZHANG Qiwu
IMRAM, Tohoku University
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SAITO Fumio
IMRAM, Tohoku University
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Saito F
Institute Of Multidisciplinary Research For Advanced Materials Tohoku University
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Saito Fumio
Institute Of Multidisciplinary Research For Advanced Materials Tohoku University
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Zhang Q
Imram Tohoku University
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Tanaka Yasumitsu
Rmc Msnc Sony Sendai Technology Center Sony Corp.
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Tanaka Yasumitsu
RMC, MSNC, Sony Corp., Sony Sendai Technology Center
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