Facile Deoxygenation of Dicarbonyl Compounds Using a Samarium Diiodide-Additive System
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概要
- 論文の詳細を見る
The reduction of α- and β-dicarbonyl compounds was investigated with samarium diiodide in the presence of additive. Diketones and ketocarboxylic acids were easily reduced at room temperature to give the mono-alcohols in good to excellent yield, and ketoester afforded the saturated ester as the major product in moderate yield. These reductions containing the reductive deoxygenation can be rapidly performed under the facile and mild conditions by this method.
- 公益社団法人日本薬学会の論文
- 2005-08-01
著者
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MASUDA Toshinobu
Daiichi College of Pharmaceutical Sciences
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KAMOCHI Yasuko
Daiichi College of Pharmaceutical Sciences
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TAKADATE Akira
Daiichi College of Pharmaceutical Sciences
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KUDO Tadahiro
Daiichi College of Pharmaceutical Sciences
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