Fragmentation of Organosulfur Compounds upon Electron Impact : II. Metastable Decomposition of Methyl and Ethyl Thiolactates
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概要
- 論文の詳細を見る
The unimolecular decomposition of the molecular ions of methyl thiolactate (1) and ethyl thiolactate (2) upon electron impact was investigated. The metastable fragmentation of 1+· is dominated by the loss of methanol. The molecular ions 2+· decompose in a variety of ways: the loss of water, the loss of ethylene, as well as the loss of ethanol are prominent. Both methyl and ethyl thiolactates do not show the fragmentation with double hydrogen transfer, which is observed in methyl lactate (3) and ethyl lactate (4).
- 日本質量分析学会の論文
- 1996-04-20
著者
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Tajima Susumu
Gunma College Of Technology
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SEKIGGCHI Osamu
Gunma College of Technology
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Sekiguchi Osamu
Gunma College of Technology
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