Unprecedented Ligand Dependent S_N2' Mechanism on the Palladium-catalyzed Nucleophilic Substitution to Bicyclic Dienyl Acetates

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概要

• 論文の詳細を見る
• 2005-03-05

著者

• SHIMIZU Isao

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• Shimizu Isao

  Department Of Applied Chemistry Graduate School Of Science And Engineering Waseda University

• DAIMON Hisashi

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• KITAMURA Takahiro

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• KAWAHARA Tamotsu

  Department of Applied Chemistry, School of Science and Engineering, Waseda University

• Daimon Hisashi

  Department Of Applied Chemistry School Of Science And Engineering Waseda University

• Kawahara Tamotsu

  Department Of Applied Chemistry School Of Science And Engineering Waseda University

• Kitamura Takahiro

  Department Of Applied Chemistry School Of Science And Engineering Waseda University

関連論文

• Catalytic Behavior of Cationic Hydridoruthenium(II) Complex, [RuH(NH_3)(PMe_3)_4]^+, in H_2-Hydrogenation and Transfer Hydrogenation of Imines
• Selective Oxidative Carbonylation of Amines to Oxamides and Ureas Catalyzed by Palladium Complexes
• Heck-type Benzylation of Olefins with Benzyl Trifluoroacetates
• Palladium Catalyzed Direct Conversion of Carboxylic Acids into Ketones with Organoboronic Acids Promoted by Anhydride Activators
• Synthesis of Unsymmetrical Ketones by Palladium-Catalyzed Cross-Coupling Reaction of Carboxylic Anhydrides with Organoboron Compounds
• General and Greener Route to Ketones by Palladium-Catalyzed Direct Conversion of Carboxylic Acids with Organoboronic Acids
• Direct Hydrogenation of Carboxylic Acids to Corresponding Aldehydes Catalyzed by Palladium Complexes
• Synthesis of Trifluoromethyl Ketones by Palladium-Catalyzed Cross-Coupling Reaction of Phenyl Trifluoroacetate with Organoboron Compounds
• Formation of a Palladalactone Complex by C-O Bond Cleavage of Diketene Promoted by a Zerovalent Palladium Complex
• Oxidative Addition of Aryl and Benzyl Trifluoroacetates to Zerovalent Palladium Complexes with Two Modes of C-O Bond Cleavage Processes
• Preparation of Acyl(carboxylato)bis(tertiary phosphine)palladium(II) Complexes by C-O Bond Cleavage of Carboxylic Anhydrides on Interaction with Palladium(0) Cpmplexes. Catalytic Hydrogenation of Carboxylic Anhydrides to Aldehydes by Palladium Complexes
• Synthesis and Properties of Dimethyl- and Monomethylbis(phosphite)palladium(II) Complexes
• Removal of a Palladium-Bound Tertiary Phosphine Ligand with Silver(I) Salts to Generate Cationic Monoorganopalladium(II) Complexes Having One Trimethylphosphine Ligand
• Comparison of the Reactivities of Neutral and Cationic Organopalladium Complexes toward CO, Isocyanides, and Olefins
• Activation of C-O and C-N Bonds in Allylic Alcohols and Amines by Palladium Complexes Promoted by CO_2. Synthetic Applications to Allylation of Nucleophiles, Carbonylation, and Allylamine Disproportionation
• Palladium-Catalyzed Cleavage of P-C Bonds in Quaternary Phosphonium Salts and Its Applications to Organic Synthesis
• Direct Hydrogenation of Carboxylic Acids to Corresponding Aldehydes Catalyzed by Palladium Complexes in the Presence of Pivalic Anhydride
• Reactivities of Neutral and Cationic Organopalladium Complexes
• Preparation and Reactivities of Acyl(carboxylato)palladium Complexes
• Synthesis and Properties of Cationic Organopalladium Complexes. Remarkable Rate Enhancement in Olefin Insertion into the Palladium-Aryl Bond by the Generation of a Cationic Palladium Complex from trans-[PdBr(Ph)(PMe_3)_2]
• Synthesis and Properties of (η^3-1-Methylallyl)palladium(II) Formates as Models of Intermediates in the Palladium-Catalyzed Reductive Cleavate of Allylic Carboxylates and Carbonates with Formic Acid
• Molybdenum - and Tungsten - Catalyzed Allylation of Aromatic Compounds with Allylic Esters and Alcohols
• Preparation a Properties of n^3-Ally(halo)tris(trimethylphosphine)ruthenium(II) Complexes and Their Derivatives
• Facile Synthesis of α-Hydroxycarboxylic Acids by Ruthenium-Catalyzed Reduction of Diallyl α-Oxalylcarboxylates with Formic Acid
• Photoconductive Plastic Holography Employing White-Light Laser : Optics and Quantum Electronics
• Facile Three-Component Synthesis of Substituted Quinolines Catalyzed by Iridium(III) Complex
• Synthesis of β-Amino Ketones by Iridium(III)-catalyzed Direct-Mannich Reaction
• Short Step Synthesis of Natural 2-Aryl-quinolones Based on Iridium-Catalyzed Three-Component Coupling Quinoline Synthesis
• One-pot Synthesis of Substituted Quinolines by Iridium-catalyzed Three-component Coupling Reaction
• One-Step Synthesis of Ethyl Quinaldates by Lewis Acid Catalyzed Three-Component Coupling Reaction of Aromatic Amines, Aliphatic Aldehydes and Ethyl Glyoxylate
• Shear Fracture Behavior on Ball Grid Arrayed Tin-Silver-Copper Solder/Pure Copper Pad Joint Interface
• Influence of Shear Height on Shear Strength of Tin-Lead Solder Ball Bonding
• 416 Microstructure and Strength Properties of Tin-Silver-Copper Solder Ball Bonded by Various Cooling Rates
• Effect of Cooling Rate on Microstructure and Strength Properties of Tin-Silver-Copper Solder Ball Bonding
• Remarkable Rate Enhancement in CO Insertion into Pd-C Bond by Generating Cationic Organopalladium Complexes [PdR(s)L_2]^+BF^-_4 (R = Alkyl Group, s = Acetone, L = Phosphine Ligands) from Neutral Monoorganopalladium Complexes [PdR(X)L_2] (X = Halide)
• Molybdenum-Catalyzed Aromatic Substitution with Olefins and Alcohols
• Facile Synthesis of (-)-Ascochlorin Using Palladium-catalyzed Three Component Coupling Reaction
• Multiple Matched Spatial Filtering with Corresponding Symbols by the Hybrid System
• Chiral Synthesis of (-)-Colletol Based on Palladium-Catalyzed Reductive Cleavage of Alkenyloxiranes with Formic Acid
• Unprecedented Ligand Dependent S_N2' Mechanism on the Palladium-catalyzed Nucleophilic Substitution to Bicyclic Dienyl Acetates
• A Novel Enantioselective Reaction. Palladium-catalyzed Enantiodistinctive Reaction of Bicyclic Allylic Compounds
• Enantioselective Nucleophilic Substitution of a 6,6-Bicyclic Dienyl Acetate by Palladium-Chiral Phosphine Catalyst
• Syntheses of Mycophenolic Acid and Its Analogs by Palladium Methodology
• One-Pot Synthesis and Fluorescence Properties of 2-Arylquinolines
• Catalytic Tricarbonylation of Alkynes with Palladium Catalysts
• Palladium-Catalyzed Oxidative Carbonylation of 1-Alkynes into 2-Alkynoates with Molecular Oxygen as Oxidant
• Phosphine-dependent Stereoselective Nucleophilic Reaction to Bicyclic Bis-μ-dichloro-η^3-allylpalladium Complexes
• Enantioselecitve Elimination of Pd-H from η^3-Allylpalladium-Tol BINAP Complexes. Evidence of Syn Elimination Pathway
• Photocycloaddition of Chloromethyl Alkenyl Ketones with Olefins in the Presence of Silver Trifluoromethanesulfonate
• Photoconductive Plastic Holography Employing White-Light Laser

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