過酸化水素, タングステン酸塩及びアンモニウム塩による塩素化エチレン類の常温酸化分解
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概要
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Chlorinated ethylenes (tetrachloroethylene (PCE), trichloroethylene (TCE), cis-1,2-dichloroethylene (cis-DCE), and 1,1-dichloroethylene (1,1-DCE)), which are soil and groundwater contaminants, were degraded by chemically reacting with hydrogen peroxide, tungstate, and ammonium salt at 25°C. The degradation reaction progressed in a neutral to slightly basic environment of pH 6-9. The degradability of the ethylenes was in the order of 1,1-DCE > TCE > cis-DCE > PCE; and this showed degradation characteristics different from those of conventional oxidizing agents (such as potassium permanganate). Furthermore, treatment by this reaction was applied to groundwater sample from a contaminated site, and all chlorinated ethylenes in the water sample were degraded except for PCE.
- 社団法人 日本水環境学会の論文
- 2004-09-10