Preparation and Exploitation of Versatile Cyclohexanoid Chiral Building Blocks

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概要

• 論文の詳細を見る

• Efficient methodology for the preparation of two enantiopure cyclohexanoids having a bicyclo [2.2. 1] octene background has been established starting from the same meso ene-1, 4-diol by employing enzymatic and catalytic asymmetric desymmetrization procedures. On the basis of their inherent convex-face selectivity and thermal fragility, we utilize these chiral tricycles as synthetic equivalents of chiral p-benzoquinone and its hydro derivatives whose potential uses have been demonstrated by diastereo- and enantio-controlled synthesis of a wide variety of biologically active natural products.

• 社団法人 有機合成化学協会の論文
• 1999-11-01

著者

• Ogasawara Kunio

  Pharmaceuticai Institute Tohoku University

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