アルケンのメタセシスによる新環化法 : 中大員炭素およびヘテロ環化合物の革新的合成戦略
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概要
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Historical background of alkene metathesis is briefly reviewed. The introduction of the Schrock Mocarbene complex and the Grubbs Ru-carbene complexes has initiated rapid development of synthetic utility of alkene metathesis. Many functional groups are tolerated without protection in the Mo and Ru catalysed metathesis. Among several synthetic applications of the alkene metathesis, the ring closing metathesis offers an extremely useful method for cyclization to give carbo-and hetero-cyclic compounds from medium to large sizes. A number of naturally occurring macrocyclic compounds have been synthesized in shorter steps by the ring closing metathesis using the Ru complex as key reaction. The alkene metathesis has brought in a dramatic change in synthetic designs of complex cyclic compounds.
- 社団法人 有機合成化学協会の論文
- 1997-12-01
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- アルケンのメタセシスによる新環化法 : 中大員炭素およびヘテロ環化合物の革新的合成戦略