Syntheses of Tungsten Diazoalkane Complexes from a Dinitrogen Complex and Diketones. Conversion of Molecular Nitrogen into Pyrazoles via the Diazoalkane Complexes as Intermediates^<1)>

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概要

• 論文の詳細を見る
• Chemical Society of Japanの論文
• 1998-11-15

著者

• ISHII Youichi

  Department of Chemistry and Biotechnology, Graduate School of Technology, The University of Tokyo

• HIDAI Masanobu

  Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo

• MIZOBE Yasushi

  Institute of Industrial Science, the University of Tokyo

• Ishii Youichi

  Department Of Applied Chemistry Faculty Of Engineering Chuo University

• Mizobe Y

  Institute Of Industrial Science The University Of Tokyo

• Mizobe Yasushi

  Institute Of Industrial Science The University Of Tokyo

• Hidai M

  Department Of Materials Science And Technology Faculty Of Industrial Science And Technology Science

• Hidai Masanobu

  Department Of Chemistry And Biotechnology Graduate School Of Engineering The University Of Tokyo

• Harada Yuji

  Institute Of Industrial Science The University Of Tokyo

関連論文

• d-f Metal Ion Interaction through Fe-C≡N-Ln Bridge between Dicyanobis(1,10-phenanthroline)iron(II) Complex and LnCl_3
• Synthesis and Characterization of Mixed-Metal Sulfido Clusters with the Cubane-Type PtMo_3S_4 Core
• Selective N-N and W-N Bond Cleavage of Tungsten Pyrrolylimido Complexes Derived from Tungsten Dinitrogen Complex
• Head-to-head Z Dimerization of Terminal Alkynes Catalyzed by Thiolate-bridged Diruthenium Complexes
• Regioselective Addition of Alcohols to Internal 1-Aryl-alkynes Catalyzed by a Triangular Heterobimetallic Ir_2 Pd Sulfido Cluster
• Hydrolysis of Diribonucleoside Monophosphate Diesters Assisted by a Manganese(II) Complex
• DFT Analysis of Cubane-Type FeIr_3S_4 Clusters : Dinitrogen Binding and Activation at the Tetrahedral Fe Site
• DFT Calculations of Cubane-Type Mo_2Ru_2S_4 Clusters. Stability of a Possible Dinitrogen Cluster and an Isolable Acetonitrile Cluster
• Agostic Interaction in Formally Five-coordinate Hydridobis[1, 3-bis(diphenylphosphino)propane]ruthenium(II)Ion
• Dinuclear Pyridine-1-Imine-Bridged Rhodium (III) Complexes, Intramolecular Carbon-Hydrogen Bond Activation
• Rational Synthesis and Crystal Structures of Heterometallic-Heterochalcogenido Cubane-Type Clusters [(Cp^*M)_2(MoOCl_2){MoCl_2(dmf)}(μ_3S)_2(μ_3-Se)_2](M = Rh, Ir)
• Synthesis and Structures of p-tert-Butyltetrathiacalix[4]arene-dihydrides of Mo(IV) and W(IV)
• Preparation of Mo and W Complexes Containing a New Linear Tetradentate Phosphine Ligand meso-o-C_6H_4(PPhCH_2CH_2PPh_2)_2 from Dinitrogen Complexes trans-[M(N_2)_2(Ph_2PCH_2CH_2PPh_2)_2] (M=Mo, W)^1
• Preparation of Sulfide-Bridged Di- or Trinuclear Pyrrolylimido and Diazoalkane Complexes Derived from a Tungsten Dinitrogen Complex
• Formation of Novel Tetradentate Phosphine Ligand o-C_6H_4(PPhCH_2CH_2PPh_2)_2 by Coupling of Two Diphosphine Ligands Bound to Low-Valent Mo or W Center.Synthesis and Structure of [M{o-C_6H_4(PPhCH_2CH_2PPh_2)_2}(Ph_2PCH_2CH_2PPh_2)] (M=Mo, W)^1
• Crystal Structure and Magnetic Properties of Two-dimensional Cyanide-bridged Bimetallic Assembly Composed of Cs^I[Mn^(3-cyanopyridine)_2{W^V(CN)_8}]・H_2O
• Synthesis, Characterization, and Reactivities of Heterobimetallic μ-Aryl Isocyanide Complexes with an Unusual Bridging Structure
• Sulfido-Bridged IrRh_2 Clusters Derived from (Hydrogensulfido)iridium Complexes and Dirhodium Fragment. Comparison between Hydrido-Hydrogensulfido and Bis(hydrogensulfido) Systems
• Internal Alkyne-to-vinylidene Isomerization at Cationic Ruthenium and Iron Complexes
• Hydrosulfido-Bridged Titanium-Ruthenium Heterobimetallic Complex : Stepwise Construction of Ti_2Ru_2S_4 Cubane-Type Sulfido Cluster
• Observation of the New κ^2C,O:κ^2C',O' Coordination Mode of 1,1,2,2-Tetraacetylethanato Ligand in a Dinuclear 1,1,1,5,5,5-Hexafluoroacetylacetonato Palladium(II) Complex
• Silylative Dimerization of Aromatic Aldehydes Catalyzed by a Thiolate - Bridged Diruthenium Complex
• Syntheses of Tungsten Diazoalkane Complexes from a Dinitrogen Complex and Diketones. Conversion of Molecular Nitrogen into Pyrazoles via the Diazoalkane Complexes as Intermediates^
• Reactivities of Molybdenum and Tungsten Diazoalkane-Isocyanide Complexes Derived from Dinitrogen Complexes^
• Reactivity of trans-[M(CO)(DMF)(Ph_2PCH_2CH_2PPh_2)_2](M=Mo, W) toward Terminal Alkynes : Synthesis of Alkynylhydrido and Vinylidene Complexes
• Preparation of Molybdenum and Tungsten Diazoalkane-Aminocarbene Complexes cis, trans-[MX_2(NN=CMePh){=C(Me)NHBu^t}(PMe_2Ph)_2] (M = Mo, W; X = Cl, Br) from Dinitrogen Complexes cis-[M(N_2)_2(PMe_2Ph)_4]
• Synthesis and Crystal Structures of Thiolate-Bridged Diruthenium Complexes Containing Two Olefinic Ligands
• Palladium-Catalyzed Formation of Aroylcobalt Complexes from Iodoarenes and Tetracarbonylcobaltate(-1) Anion and Syntheses of the Model Intermediate Complexes
• Preparation and Characterization of Rhodium C_ Complexes [Rh(acac)(L)_2(C_)] (L = py, 4-Mepy, 3,5-Me_2py)
• Stepwise Syntheses of a Series of Thiolate-Bridged Diruthenium Complexes [Cp^*RuBr(μ-SPr^i)_2RuCp^*X](Cp^*=η^5-C_5Me_5;X=SPr^i, alkynyl, H) and [Cp^*RuRr(μ-SPr^i)_2RuCp^*H](R=CH_2Ph, CH_2CH_2Ph). Facile Dinuclear Reductive Elimination of PhCH_3 from [Cp^*
• Rh_4S_7 and Ir_3CuS_6 Clusters with Di-and Trisulfido Ligands Derived from Dinuclear Hydrogensulfido Complexes
• Copper(II) Mixed Ligand Complex with an N-Alkylated Diamine and a New β-Diketonate
• Toward Direct Synthesis of Organonitrogen Compounds from Dinitrogen: The Chemistry of Diazoalkane Complexes Derived from Dinitrogen Complexes
• Synthesis and Molecular Structure of Tetranuclear Tungsten-Gallium Complexes with Bridging Dinitrogen Ligands^1
• Synthesis of Boryldiazenido Complexes from Tungsten Dinitrogen Complexes^1
• Synthesis and Reactivities of Sulfido-bridged Ir-W and Ir-Re Heterodinuclear Complexes with Imido Ligands
• Synthesis and Characterization of Hydride and Carbonyl RuMo_3S_4 Cubane Clusters
• Intramolecular Cyclization of Aminoalkynes Catalyzed by PdMo_3S_4 Cubane Clusters
• Synthesis and Skeletal Transformation of Cyanamido(2-)- and Cyanamido(1-)-Bridged Ruthenium Complexes with Hexamethylbenzene Ligands
• Regioselective hydrogenation of unsymmetrically substituted cyclic anhydrides catalyzed by ruthenium complexes with phosphine ligands.
• Diazoalkane complexes of molybdenum.
• Homologation of methyl esters catalyzed by ruthenium-cobalt bimetallic systems.
• The Electrochemical Behavior of the Low-valent Transition Metal Complexes. II. Iron(0)-2,2′-Bipyridine Complexes
• Nucleophilic reactions of hydrazido(2-) complexes of molybdenum and tungsten with succinyl dichloride and phenyl isocyanate.
• Telomerization of isoprene with dialkylamine catalyzed by palladium complexes.

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