Theoretical Study of the Electronic Structure of 2,2'-Bisilole in Comparison with 1,1'-Bi-1,3-cyclopentadiene : σ^*-π^* Conjugation and a Low-Lying LUMO as the Origin of the Unusual Optical Properties of 3,3',4,4'-Tetraphenyl-2,2'-bisilole^<1)>
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概要
- 論文の詳細を見る
- Chemical Society of Japanの論文
- 1996-08-15
著者
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Tamao Kohei
Institute For Chemical Research Kyoto University
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Yamaguchi Shigehiro
Institute For Chemical Research Kyoto University
関連論文
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- New Chiral Diphosphines, 2, 3-Bis(Siloxy)-1, 4-bis(diphenylphosphino)butanes, and Their Cationic Rh(I) Complexes : Synthesis and Structures
- Silole-Acetylene π-Electronic Systems with Low Bandgaps:Synthesis, Structure, and UV-vis Absorption Spectra of 2, 5-Diethynylsiloles Derivatives and Their Polymers
- Substituent-Control of Two Modes of Intramolecular Reactions of Allyloxy-Silyllithiums and Propargyloxy-Silyllithiums
- Stereoselective Formation of Cyclopropylsilane through Intramolecular Rearrangement of [(Allyloxy)dimesitylsilyl]lithiums
- The First Alkali Metal Selenothioates: Synthesis and Molecular Structure
- Nucleophilic Addition of a Divalent Silicon Species Bearing the 8-Dimethylamino-1-naphthyl Group to Diphenylacetylenes to Form the 1-Amino-1-silaphenalene Skeleton
- Trimerization of a Divalent Silicon Species Bearing the 8-Dimethylamino-1-naphthyl Group Accompanied by the Migration of Methyl and Dimethylamino Groups
- Wurtz - type Coupling Reaction of Pseudo - pentacoordinate Halodisilanes Using Magnesium : Enhanced Reactivity of the Silicon - Halogen Bond by Intramolecular Amine - Coordination to Silicon
- Reaction of {Tris[2-(dimethylamino)phenyl] germyl} lithium with Elemental Selenium : Formation of 2, 2, 4, 4- Tetrakis [2-(dimethylamino) phenyl]- 1, 3, 2, 4- diselenadigermetane
- Boron-Metal Exchange Reaction of Silylboranes with Organometallic Reagents: A New Route to Arylsilyl Anions
- Intramolecular Cyclization Reaction via a Sterically Protected Episelenonium Ion Intermediate
- Endo-Endo Mode Intramolecular Reductive Cyclization of Cyclization of Cyclic 1,2-Bis (silylethynyl) benzenes
- Theoretical Study of the Electronic Structure of 2,2'-Bisilole in Comparison with 1,1'-Bi-1,3-cyclopentadiene : σ^*-π^* Conjugation and a Low-Lying LUMO as the Origin of the Unusual Optical Properties of 3,3',4,4'-Tetraphenyl-2,2'-bisilole^
- A New Chiral Molecular Square with D_4 Symmetry Composed of Enantiomerically Pure Spirosilane
- Enhanced Leaving Ability of Methoxy Group and Retarded Deprotonation on the Carbon Atom Linked to the 1-Position of 8-Phosphino- or 8-Amino-naphthalene
- Preparations and Reactions of Functionalized Silyllithiums