A Remarkable Difference in the Reactivity between cis-and trans-Silylplatinum Complexes toword Insertion of Acetylene

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概要

• 論文の詳細を見る
• 1995-11-05

著者

• ONITSUKA Kiyotaka

  Department of Applied Chemistry, Faculty of Engineering, Osaka City University

• OZAWA Fumiyuki

  Department of Apploed Chemistry, Faculty of Engineering, Osaka City University

• SONOGASHIRA Kenkichi

  Department of Applied Science and Chemistry, Faculty of Engineering, Fukui University of Technology

• Ozawa Fumiyuki

  Department Of Applied Chemistry Faculty Of Engineering Osaka City University

• HAYASHI Tamio

  Department of Chemistry, Graduate School of Science, Kyoto University

• HIKIDA Toshihiko

  Graduate School of Pharmaceutical Sciences, Hokkaido University

• Onitsuka Kiyotaka

  Department Of Applied Chemistry Faculty Of Engineering Osaka City University

• Hayashi Tamio

  Department Of Chemistry Graduate School Of Science Kyoto University

• Sonogashira K

  Department Of Applied Science And Chemistry Faculty Of Engineering Fukui University Of Technology

• Sonogashira Kenkichi

  Department Of Applied Chemistry Faculty Of Engineering Osaka City University

• Hikida Toshihiko

  Graduate School Of Pharmaceutical Sciences Hokkaido University

• Hayashi Tamio

  Department Of Chemistry Faculy Of Science Kyoto University

関連論文

• Synthesis and Structure of a Novel 1, 1′-Ferrocenediyldiplatinum Complex Having μ_3 (2S, N) -NCS Ligands
• Synthesis and Structure of Novel Thiolato-, Selenolato- or Tellurolato-Bridged 1,1'-Ferrocenediyldiplatinum Complexes
• C-H Bond Activation of the Ferrocenyl Group in the Reaction of σ-Ferrocenylplatinum Complex with Dimethyl or Diethyl Acetylenedicarboxylate
• Synthesis and Structure of Novel Metallacycle Complexes of Ruthenium Derived from 1,1'-Dialkynylferrocene
• Synthesis, Molecular Structure and Reactions of a Novel μ-σ,π-Cyclopentadienediyl Platinum-Manganese Complex
• Synthesis and Molecular Structure of 1,1'-Ferrocenediyl Bis(dimethylsilylene) Bridged Triruthenium Dihydrido Cluster, [Ru_3(μ-H)_2(μ-SiMe_2C_5H_4FeC_5H_4SiMe_)(CO)_]
• Ligand Exchange Reactions to Thienylene-Bridged Dinuclear Platinum Complex with Diphosphines. Synthesis and Molecular Structure of Diphosphine-Bridged μ-2,5-Thienylene Diplatinum Complex
• Reactions of 1-Ferrocenyl and 1,1'-Ferrocenediyl Platinum Complexes with Copper Acctylide. Synthesis and Molecular Structure of a Novel 1,1'-Ferrocenediyl Pt_2Cu_3 Acetylide Complex
• Synthesis and Properties of (η^3-1-Methylallyl)palladium(II) Formates as Models of Intermediates in the Palladium-Catalyzed Reductive Cleavate of Allylic Carboxylates and Carbonates with Formic Acid
• Dehydrogenative Silylation of Ketones Catalyzed by Diphosphinidenecyclobutene-Coordinated Platinum(II) Complexes
• A New Process for C-Si Bond Formation from cis-Alkyl(silyl)platinum(II)Complexes
• Ring - opening Metathesis Polymerization of Norbornene in the Presence of Heteroatom - substituted Vinylic Compounds : Highly Selective Synthesis of End - functionalized Poly(norbornene)s
• Redox Catalysis of Halide Ion for Formal Cross-dehydrogenative Coupling : Bromide Ion-catalyzed Direct Oxidative α-Acetoxylation of Ketones
• PB33 ASYMMETRIC SYNTHESIS OF β-HYDROXYL-α-AMINO ACIDS BY ASYMMETRIC ALDOL REACTION OF α-ISOCYANOCARBOXYLATES CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-GOLD (I) COMPLEXES
• Insertion of Phenylacetylene into cis-Silyl(stannyl)platinum Complexes
• Platinum-catalyzed 1,4-Addition of Arylboronic Acids to β-Substituted α,β-Unsaturated Ketones
• Synthesis of Alkyl[hydrotris(pyrazolyl)borato]ruthenium(II) Complexes by Transmetallation
• Reactions of Alkenylruthenium (II) Complexes with Hydrosilane : C-Si vs C-H Bond Formation
• The New Possibility of Vinylideneruthenium(II)Complexes Derived from Terminal Alkynes:Ring-Opening Metathesis Polymerization of Norbornene Derivatives
• Regio- and Stereoselective Hydrosilylation of 1, 4-Bis(trimethylsilyl)-3-buten-1-ynes
• A Remarkable Difference in the Reactivity between cis-and trans-Silylplatinum Complexes toword Insertion of Acetylene
• Insertion of Electron-Deficient Olefins into the C_H Bond of 2-Furanyl-and 2-Thienylplatinum Complexes
• Silver-catalyzed Alkyl-Alkyl Homo-coupling of Grignard Reagents
• Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines
• Preparation of a New MOP Ligand Containing a Long-Chain Alkyl Group and Its Use for Palladium-Catalyzed Asymmetric Hydrosilylation of Cyclic 1,3-Dienes
• Modification of Chiral Monodentate Phosphine (MOP) Ligands for Palladium-Catalyzed Asymmetric Hydrosilylation of Styrenes
• Iron-catalyzed Pinacol Coupling of Aryl Ketones with a Phenyltitanium Reagent : A New Type of Catalytic Reaction
• Reactions of 1, 1'-Dialkynylferrocene with Octacarbonyldicobalt
• Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids
• Palladium-Catalyzed Synthesis of Butatrienes
• Rhodium-Catalyzed Asymmetric Addition of Organo-Boron and -Titanium Reagents to Electron-Deficient Olefins
• Cobalt-catalyzed Coupling of Alkenyl Triflates with Aryl and Alkenyl Grignard Reagents
• Palladium-catalyzed Decarboxylative [4 + 1] Cyclization of γ-Methylidene-δ-valerolactones with Isocyanides
• Ruthenium-catalyzed 1,4-Addition of Organoboronic Acids to α,β-Unsaturated Ketones
• Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Aldehydes Catalyzed by a Chiral Diene-Rhodium Complex
• Iron-catalyzed Oxidative Coupling of Alkylamines with Arenes, Nitroalkanes, and 1,3-Dicarbonyl Compounds
• Platinum-catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α,β-Unsaturated Ketones
• Nickel-catalyzed Conjugate Addition of Arylboron Reagents to α,β-Unsaturated Carbonyl Compounds with the Aid of a Catalytic Amount of an Alkyne
• Concise Synthesis of β,β-Diaryl Esters and Ketones from Ethynylcarbonyl Compounds by Rhodium-catalyzed Double Arylation with Arylboroxins
• Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. I. Preparation of chiral ferrocenylphosphines.
• Determination of Enantiomeric Purity of 1-Phenylalkanols Using a Chiral NMR Shift Reagent
• Preparation of (R)-N,N-dimethyl-1-(2-(diphenylphosphino)ferrocenyl)-2-propanamines and asymmetric Grignard cross-coupling catalyzed by nickel complexes with the phosphine ligands.

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