Gas Phase Basicities of Acetophenones toward Trimethylsilyl Cation

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概要

• 論文の詳細を見る
• 1992-03-05

著者

• TSUNO Yuho

  Institute for Fundamental Research of Organic

• Fujio M

  Institute For Materials Chemistry And Engineering Kyushu University

• Kang Chul

  Department Of Chemistry Inha University

• Fujio Mizue

  Institute For Materials Chemistry And Engineering Kyushu University

• Tsuno Y

  Institute For Fundamental Research Of Organic Chemistry Kyushu University

• Mishima M

  Kyushu Univ. Fukuoka

• Mishima Masaaki

  Institute For Fundamental Research Of Organic Chemistry And Department Of Chemistry And Physics Of C

• FUJIO Mizue

  Department of Chemistry, Faculty of Science, Kyushu University

• KANG Chul

  Institute for Molecular Science

• Fujio M

  Kyushu Univ. Fukuoka

関連論文

• Solvent Effects on Anchimerically Assisted Solvolyses. II.^ Solvent Effects in Solvolyses of threo-2-Aryl-1-methylpropyl p-Toluenesulfonates
• Solvent Effects on Anchimerically Assisted Solvolyses. III.^ Solvent Effects on the Solvolyses of (1-Arylcycloalkyl)methyl p-Toluenesulfonates
• THE STUDY OF ^O-SCRAMBLING IN THE MENSCHUTKIN REACTION OF p-METHYLBENZYL TOSYLATE WITH N,N-DIMETHYLANILINES IN ACETONITRILE
• SOLVENT EFFECT ON THE SOLVOLYSIS OF BENZONORBORNEN-9(ANTI)-YL m-NITROBENZENESULFONATE
• SUBSTITUENT EFFECTS ON THE REARRANGEMENT RATIO IN SOLVOLYSIS PRODUCT OF 2-ARYLETHYL TOSYLATES
• CARBON-13 NMR STUDIES ON REACTION MECHANISMS (V) : SALT EFFECTS ON ACETOLYSIS OF 2-(p-ANISYL)ETHYL TOSHYLATE
• CARBON-13 NMR STUDIES ON REACTION MECHANISMS (III) : ACETOLYSIS OF p-ANISYLETHYL TOSYLATE
• CARBON-13 NMR STUDIES OF REACTION MECHANISMS (II) : ACETOLYSIS OF PHENYLETHYL TOSYLATE
• Thermodynamic Stabilities and Resonance Demand of Aromatic Radical Anions in the Gas Phase
• Substituent Effect on Gas Phase Basicity of cis 2-Phenyl-2-butene. Intrinsic Resonance Demand of α,α-Dialkylbenzyl Carbocations
• The β-Silicon Effect : III. Substituent Effects of the β-Si-Aryl Moiety in the Solvolysis of 1-Aryl-2-(aryldimethylsilyl)ethyl 3,5-Dinitrobenzoates
• The β-Silicon Effect. II. Substituent Effects on the Solvolysis of 1-Aryl-2-(aryldimethylsilyl)ethyl 3,5-Dinitrobenzoates
• The γ-Silicon Effect. II. The Substituent Effect on the Solvolysis of 3-(Aryldimethylsilyl)-2,2-dimethylpropyl p-Bromobenzenesulfonates
• The γ-Silicon Effect. I. Solvent Effects on the Solvolyses of 2,2-Dimethyl-3-(trimethylsilyl) propyl and 3-(Aryldimethylsilyl)-2,2-dimethylpropyl ρ-Toluenesulfonates
• Solvent Effects on the Solvolysis of Benzyl Tosylates. Behavior of Derivatives with Electron-Donating Substituents
• Solvent Effects on the Solvolysis of p-Nitrobenzyl and 3,5-Bis(trifluoromethyl)benzyl p-Toluenesulfonates^
• THE STUDY OF ^O-SCRAMBLING ON THE SOLVOLYSIS OF α-t-BUTYLBENZYL TOSYLATE
• SOLVOLYSIS OF 1,1,3,3-TETRAMETHYLINDAN-2-YL SULFONATES
• Pyrolytic Elimination of 1-Ary1-2-(trimethylsilyl)ethyl Acetates via Two Distinct Pathways
• SOLVENT EFFECTS ON THE SOLVOLYSIS OF NEOPHYL TOSYLATES
• Substituent Effects in the 1,1-Diphenylcarbenium Systems : Hydration and Bromination of 1,1-Diphenylethylenes
• Non Linearity and Non-Additivity of Substituent Effects in Solvolysis of 1, 1-Diphenylethyl p-Nitrobenzoates
• Theγ-Silicon Effect. IV.^1 The Solvolysis Mechanism of 3-(Aryldimethylsilyl)propyl p-Toluenesulfonates
• Substituent Effects on the Solvolysis Rates and Gas Phase Stabilities of 1,2,2-Trimethyl-1-phenylpropyl and 1,2,2-Trimethyl-1-(2-methylphenyl)propyl Systems
• Thermodynamic Stabilities of Phenonium Ions Based on Bromide-Transfer Equilibria in the Gas Phase^
• Substituent Effects on the Solvolysis of 2, 2, 2-Trifluoro-1, 1-diphenylethyl Tosylates. II. ^ 3-Chlorophenyl-and 3, 5-Dichlorophenyl-Fixed Systems
• Substituent Effects on the Solvolysis of 1,1-Diphenyl-2,2,2-trifluoroethyl Tosylates: Comparison between Symmetrically Disubstituted and Monosubstituted Systems
• Gas-Phase Substituent Effects in Highly Electron-DeGFicient Systems. II. Stabilities of 1 -Aryl-2, 2, 2-trifluoroethyl Cations Based on Chloride-Transfer Equilibria^
• Resonance Effects in the Solvolysis of α-τ-Butyl-α-.neopentylbenzyl and α-τ-Butyl-α-isopropylbenzyl ρ-Nitrobenzoates
• Gas-Phase Substituent Effects in Higbly Electron-Deficient Systems. I. Intrinsic Stabilities of 1-Aryl-1-(trifluoromethyl)ethyl Cations^
• Changes of the Aromatic Character of the Ring in Exocyclically Substituted Derivatives of Benzylic Cation as a Result of Varying Charge at the exo-Carbon Atom
• Gas-Phase Substituent Effects in Stabilized Benzylic Carbocations. Basicities of Benzaldehydes, Acetophenones, and Methyl Benzoates in the Gas Phase^
• Gas Phase Basicities of Phenylacetylenes. Intrinsic Resonance Demand of the 1-Phenylvinyl Cation
• Substituent Effects on Chloride Transfer Equilibrium in the Gas Phase. Intrinsic Resonance Demand of Benzyl Cation ^
• Prediction of gas-particle dynamics and heat transfer in a two-dimensional spouted bed
• The Effect of Temperature on the Minimum Fluidization Velocity Calculated by Distinct Element Method
• Numerical Analysis of Granular Convection in Two-Dimensional Pulsating Fluidized Bed
• Numerical Analsis of Density Wave in Dense Gas-Solid Flows in a Vertical Pipe
• Kinetic Isotope Effects for Addition of Lithium Pinacolone Enolate to Benzaldehyde
• Gas-Phase Acidities of Acetophenone Oximes. Substituent Effect and Solvent Effects
• VARYING RESONANCE DEMANDS IN CARBOCATIONIC SOLVOLYSES
• Gas Phase Basicities of α-Trimethylsilylstyrenes. Intrinsic Effect of α-Trimethylsilyl Group on the Stability of Carbenium Ions
• GAS PHASE SUBSTITUENT EFFECT ON BASICITY OF PHENYLACETYLENE : INTRINSIC RESONANCE DEMAND OF A VINYLIC CATION
• Substituent Effect on the Gas Phase Basicity of Pyridine N-Oxide
• Substituent Effect on the Gas Phase Basicity of α-t-Butylstyrene. Coplanarity and Resonance Demand of a Benzylic Carbocation
• Binding Interaction of The Trimethylsilyl Cation with Oxygen and Nitrogen Bases in the Gas Phase. Acetopheones, Benzaldehydes, Pyridines, Anilines, and N,N-Dimethylanilines
• Theoretical Study on Carbocation Formation Reactions. Resonance Demands and Transition Structures
• Gas Phase Substituent Effect on Basicity of Phenylacetylene. Intrinsic Resonance Demand of Phenylvinyl Cation
• Study of the Time-resolved IR Spectrum of α-Arylvinyl Cations Generated by Laser Flash Photolysis
• SOLVENT EFFECTS ON THE SOLVOLYSIS OF p-NITRO- AND 3,5-BIS(TRIFLUOROMETHYL)BENZYL TOSYLATES
• SOLVENT EFFECTS ON THE SOLVOLYSIS OF BENZYL TOSYLATES
• Stability of Complexes of Phenylacetylides and Benzyl Alkoxides with Methanol in the Gas Phase. Acid-Base Correlation in the Ionic Hydrogen-Bond Strength
• Substituent Effects on the Gas Phase Acidity of Phenylacetylenes and Benzyl Alcohols
• Substituent Effect on Electron Affinity of 2,6-Dimethylnitrobenzene
• Effect of the Twisted Nitro Group on Gas Phase Acidities of Phenol, toluene, Aniline, and Benzoic Acid. Steric Inhibition of Intrinsic Resonance Effect
• Gas Phase Basicities of Styrenes toward Trimethylsilyl Cation. Structure and Stability of Me_3Si-Styrene^+ Complexes
• Gas Phase Basicities of Acetophenones toward Trimethylsilyl Cation
• SUBSTITUENT EFFECT ON THE GAS PHASE BASICITY OF PYRIDINE N-OXDE
• Reaction of Magnesium Pinacolone Enolate with Benzaldehyde : Polar or ET Mechanism?
• GAS PHASE SUBSTITUENT EFFECT OF N,N-DIMETHYLBENZAMIDE : RESONANCE DEMAND IN A HIGHLY STABILIZED CARBOCATION SYSTEM
• Experimental and Theoretical Studies of the Possible and Preferred Site of Protonation in Polyfunctional N^1, N^1-Dimethyl-N^2-benzoylformamidine in the Gas Phase
• SOLVENT EFFECT ON THE SOLVOLYSIS OF α-t-BUTYLBENZYL TOSYLATE
• SUBSTITUENT EFFECT ON THE SOLVOLYSIS OF α-t-BUTYLBENZYL TOSYLATES : SOLVENT MODIFICATION OF SUBSTITUENT EFFECTS
• EFFECTS OF THE TWISTED NITRO GROUP ON ^C CHEMICAL SHIFTS OF BENZENE DERIVATIVES
• SUBSTITUENT EFFECTS ON GAS PHASE BASICITIES OF ACETOPHENONES
• SUBSTITUENT EFFECTS ON CARBON-13 MNR CHEMICAL SHIFTS (III) : p-SUBSTITUTED FLUOROBENZENES
• THE SUBSTITUENT EFFECT ON CARBON-13 NMR CHEMICAL SHIFTS (II) : ^C CHEMICAL SHIFTS OF p-SUBSTITUTED NITROBENZENES
• CARBON-13 NMR CHEMICAL SHIFTS OF MONOSUBSTITUTED BENZENES
• CARBON-13 NMR CHEMICAL SHIFTS OF SUBSTITUTED ACETOPHENONES IN SULFURIC ACID
• NMR CHEMICAL SHIFTS OF HYDROGEN-BOUNDING HYDROXYL PROTON OF SUBSTITUTED PHENOLS IN ACETONITRILE
• SUBSTITUENT EFFECTS ON CHLORIDE TRANSFER EQUILIBRIA IN THE GAS PHASE
• Substituent effects. XXI. Solvolysis of benzyl tosylates.
• Substituent effects. XVIII. The resonance demand in the acetolysis of neophyl brosylates.
• Substituent effects. XX. Highly electron-deficient carbocation solvolyses.
• The Substituent Effect. IV. Proton NMR Chemical Shifts of Phenols
• Substituent effects. 22. The solvolysis of .ALPHA.-t-butylbenzyl tosylates.
• Substituent effects. XIX. Solvolysis of 1-aryl-1-(trifluoromethyl)ethyl tosylates.
• The Substituent Effect. VI. Inductive and π-Electronic Effects in the Phenol Hydroxyl Chemical Shifts in DMSO
• The Substituent Effect. V. NMR Chemical Shifts of Hydrogen-bonding Hydroxyl Proton of Phenols in DMSO
• Amination of Phenylketene Revisit. Substituent Effect on Reactivity
• Gas-Phase Acidities of α- and α,α-SO_2CF_3-Substituted Toluenes. Varying Resonance Demand in the Electron-Rich System
• DFT Computations to Simulate the IR Spectrum of a Transient Intermediate Generated upon Laser Flash Photolysis of Triaryphosphines

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