Stereochemical Recognition in Lipase Catalysis (〔油化学〕創立40周年記念特集号) -- (トピックス)
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概要
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Enantioselective lipase catalysis, in either aqueous or organic media, is becoming increasingly important in preparative synthetic chemistry. Despite poor enantiotopic selectivity in hydrolyzing triacylglycerols, lipases proved to be remarkable asymmetric agents in resolving carboxylic acids and alcohols. Thus, this article discusses (1) the general catalytic features of lipases, (2) the basic principles that govern the stereochemical selectivity of lipase catalysis in aqueous and organic media for the preparation of optically active compounds, and (3) experimental parameters important to lipase-catalyzed enantioselective esterification in organic solvents.
- 社団法人 日本油化学会の論文
- 1992-09-20
著者
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Chen Ching-shih
Department Of Pharmacognosy & Environmental Health Sciences College Of Pharmacy University Of Rh
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LIU Yeuk-Chuen
Department of Pharmacognosy & Environmental Health Sciences College of Pharmacy, University of Rhode
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Liu Yeuk-chuen
Department Of Pharmacognosy & Environmental Health Sciences College Of Pharmacy University Of Rh