Synthesis of Azetidines from Imines with 2, 3-Dihydrofuran under High Pressure

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概要

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• 6, 7-Aryl-2-oxa-7-azabicyclo[3. 2. 0]heptane compounds were obtained from arylimines with 2, 3-dihydrofuran under high pressure. When benzylidene aniline used as imine, 6, 7-diphenyl-2-oxa-7-azabicyclo[3. 2. 0]heptane was obtained 66% yield with 87% selectivity. This reaction was promoted by pressure and the yield and the selectivity of the reaction were increased by temperature. The mechanism of the reaction was considered zwittenonic route was favored.

• 日本高圧力学会の論文

著者

• Taguchi Y

  National Institute Of Materials And Chemical Research

• Oishi A.

  National institute of Materials and chemical research

• Taguchi Y.

  National institute of Materials and chemical research

• Tsuchiya T.

  National institute of Materials and chemical research

• SHIBUYA I.

  National institute of Materials and chemical research

関連論文

• Synthesis of Azetidines from Imines with 2, 3-Dihydrofuran under High Pressure

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