Miyano Sotaro | Department of Applied Chemistry, Faculty of Engineering, Tohoku University

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著作論文

Tetra- and Di-Nuclear Copper(II) Complexes with Stereoisomers of Sulfinylcalix[4]arene Arising from the Disposition of Four S=O Groups
Metal-Ion Extractability of Sulfur-Bridged Oligomers of Phenol ; Distinct Effect of the Number of Sulfur Bridges Rather Than the Cyclic/Acyclic Form^1
Complexing Ability of p-tert-Butylthiacalix[6]arene toward Metal Ions. Predominant Effect of Coordination by the Bridging Sulfur Rather than That of the Ring-Size
Synthesis and Structural Characterization of a Pd^ Complex with p-tert-Butylsulfinylcalix[4]arene
Sulfonylcalix[4]arene as a Bis-Tridentate Facial Ligand: Syntheses and Structures of Dinuclear Complexes, [M_2(L)(H_2O)_2(dmf)_4] (M = Co(II),Ni(II);H_4L = p-tert-Butylsulfonylcalix[4]arene
Coordination of Epithio Groups of p - tert - Butylthiacalix [4]arene in a Zn^ Complex Studied by X-Ray Crystallography
High Complexation Ability of Thiacalixarene with Transition Metal Ions. The Effects of Replacing Methylene Bridges of Tetra(p-t-butyl)calix[4]arenetetrol by Epithio Groups
Topological Variation between Hexa- and Trithiacalix[6]arene-Copper(II) Complexes : From Sphere to Wheel by Reducing the Number of the Sulfur Bridges
A p-tert-Butyldithiacalix[4]arene-Copper(II) Complex Having Double-cone Shape of Unique Heteroditopie Inclusion Behavior
p-tert-Butylthiacalix[6]arene as a Clustering Ligand. Syntheses and Structures of Co^_5, Ni^_4, and Mixed-Metal M^Ni^_4 (M=Mn, Co, and Cu) Cluster Complexes, and a Novel Metal-Induced Cluster Core Rearrangement
A New Chiral Stationary Phase for Gas Chromatography by Use of a Chiral Thiacalix [4] arene Derivative
Almost Complete Removal of Trace Amount of Halogenated Organic Compounds in Water:An Approach by Use of a Combination of Water-Soluble Thiacalixarene and Ion-Exchange Resins
A New Water-Soluble Host Molecule Derived from Thiacalixarene
Lewis Acid-Mediated Carboxylation of Aryl- and Allylsilanes with Carbon Dioxide
Lewis Acid-Mediated Carboxylation of Fused Aromatic Compounds with Carbon Dioxide
Interconversion between syn and anti Conformations of 1, 3-Bis (O-cyanomethyl)-p-tert-butylthiacalix[4]arene
Synthesis and Optical Resolution of an anti-O, O'-Dialkylated Calix[4]arene
Ester-Mediated Nucleophilic Aromatic Substitution of 2, 3-Alkylidenedioxybenzoic Esters by Aryl Lithium Reagents
New Entry to Chiral Base Catalyst. Asymmetric Michael Addition of α-Substituted β-Keto Esters to Methyl Vinyl Ketone Catalyzed by Podand-type Alkali Metal 2'-Substituted 1, 1'-Binaphthalen-2-oxides
Highly Selective Luminescence Determination of Terbium at the Sub-ppb Level with Sulfonylcalix[4]arene-p-tetrasulfonate
An Investigation of the Inherent Chiral Induction Ability of Axially Chiral 1,1'-Binaphthalene Framework in the Prelog's Atrolactic Acid Synthesis
Chelating Adsorbent for Heavy Metal Ions Prepared by Loading Anion-Exchange Resin with Thiacalix[4]arenetetrasulfonate
α-Methoxy-α-trifluoromethylpropionic Acid (MTPr). A New Chiral Derivatizing Reagent for GC Separation of Enantiomeric Amino Acids
Design and Synthesis of Chiral Stationary Phase Derived from (S)-[10]Paracyclophane-13-carboxylic Acid for the HPLC Separation of Enantiomers
Use of axially chiral 2'-methoxy-1,1'-binaphthyl-2-carboxylic acid as chiral derivatizing agent for discrimination of enantiomeric alcohols and amines by 1H NMR.
The asymmetric Ullmann coupling reaction of chiral diol diesters of 1-bromo-2-naphthoic acid and 2-halo-3-nitrobenzoic acids: Highly diastereoselective synthesis of atropisomeric 6,6'-dinitrodiphenic acids.
Carbon-carbon bond formation by use of chloroiodomethane as a C1 unit. I. Formation of chloromethyltriphenylphosphonium iodide, and its application for the Wittig chloromethylenation of aldehydes and ketones.
Asymmetric synthesis of axially chiral, unsymmetrical diphenic acids via intramolecular Ullmann coupling reaction.
The Ullmann coupling reaction of axially chiral (S)-2,2'-bis(1-iodo-2-naphthyloxycarbonyl)-1,1'-binaphthyl.
The asymmetric Ullmann coupling reaction of (S)-2,2'-bis(1-bromo-2-naphthoyloxy)-1,1'-binaphthyl revisited. Formation of 24-membered optically pure cyclic dimer as well as 12-membered cyclic monomer.
Carbon-carbon bond formation by the use of chloroiodomethane as a C1 unit. IV. The Mannich reaction of ketones by means of dihalomethane and secondary amine.
Carbon-carbon bond formation by the use of chloroiodomethane as a C1 unit. III. A convenient synthesis of the Mannich base from enol silyl ether by a combination of chloroiodomethane and N,N,N',N'-tetramethylmethanediamine.
Selective oxidation of 2-bromo-m-xylene to 2-bromo-3-methylbenzoic acid or 2-bromoisophthalic acid.
Carbon-carbon bond formation by the use of chloroiodomethane as a C1 unit. II. The preparation and synthetic application of 1-chloro-3-iodoheptane.
Oxygen-accelerated generation of the bromocarbenoid reagent of zinc from diethylzinc and bromoform. Bromocyclopropanes from olefins.
Synthesis of Optically Active Polyamides Having Axially Dissymmetric 1,1'-Binaphthalene-2,2'-dicarboxylic Acid Component and Their Optical Resolution Ability as Chiral Adsorbent for HPLC.
A practical method for optical resolution of 1,1'-binahthyl-2,2'-dicarboxylic acid via 1-phenylethylamides.

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